Preparation and SO<sub>2</sub> Absorption/Desorption Properties of Crosslinked Poly(1,1,3,3‐Tetramethylguanidine Acrylate) Porous Particles
Why this work is in the frame
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Bibliographic record
Abstract
Abstract Summary: Novel crosslinked porous particles based on the ionic copolymer of 1,1,3,3‐tetramethylguanidine acrylate (TMGA) and N , N ‐methylenebisacrylamide (MBA) were prepared via an inverse suspension polymerization using cyclohexane as continuous phase and Span 60 as the dispersant. The SO 2 absorption–desorption properties of the P(TMGA‐ co ‐MBA) particles were studied for the first time. The particles showed excellent SO 2 absorption properties: high capacity and rate. These absorption properties, as well as the particle volume, shape, and morphology, remained unchanged during the SO 2 absorption–desorption cycles. The material appeared to be a good candidate as SO 2 absorbent for fuel gas desulfurization (FGD) and purification of other SO 2 ‐containing gases. Optical microscope image of the P(TMGA‐ co ‐MBA) porous particles. magnified image Optical microscope image of the P(TMGA‐ co ‐MBA) porous particles.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it