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Record W2013105369 · doi:10.1021/la991028v

Studies on the Interfacial Composition and Thermodynamic Properties of W/O Microemulsions

2000· article· en· W2013105369 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueLangmuir · 2000
Typearticle
Languageen
FieldChemistry
TopicSurfactants and Colloidal Systems
Canadian institutionsSt. Francis Xavier University
Fundersnot available
KeywordsMicroemulsionDilutionAlkaneHeptanePulmonary surfactantChemistryThermodynamicsPhase (matter)Chemical engineeringOrganic chemistryHydrocarbon

Abstract

fetched live from OpenAlex

The interfacial and thermodynamic properties of water/CPC/alkanol/alkane (C 6 and C 7 ) and water/DDBS/1-pentanol/ n -heptane w/o microemulsion systems were investigated by the method of dilution. The rationale for the equation used by earlier workers to process their data was clarified, and the criticism made in a recent paper on the relationships used in the dilution method was shown to be unjustified. The composition of the cosurfactant and the surfactant in the interfacial region, the distribution of the cosurfactant between the interfacial region and the continuous oil phase, and the energetics of transfer of the cosurfactant from the oil to the interface were estimated. A correlation between the free energy of transfer and the alkanol carbon number was examined.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.267

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.238
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it