Assessing organic phosphorus status of Cerrado oxisols (Brazil) using <sup>31</sup>P-NMR spectroscopy and phosphomonoesterase activity measurement
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Bibliographic record
Abstract
Plant production in the Brazilian savannas, also known as the Cerrados, is limited mainly by low P availability in soils. Little is known about the P status in the Cerrados region, despite its increasing significance for the country’s agriculture. 31 P-NMR spectroscopy of alkali extracts and phosphomonoesterase (PME) activity measurements were used to study forms of P and their stability in oxisols of natural and pasture systems. Total P content (Pt) in topsoils ranged from 301 to 456 mg kg -1 and organic P content (Po) from 84 to 194 mg kg -1 with the highest values under natural vegetation. The estimation of forms of soil P with different lability (provided by NaHCO 3 and NaOH extractions) showed little difference between natural vegetation and pastures, but the proportions of Po extracted suggest the importance of organically bound P as a source of plant-available P. All NMR spectra showed signals of organic P (monoesters and diesters) and inorganic P forms (orthophosphate and pyrophosphate), with little influence of land use. Organic P appears to be mainly in the form of stable phosphomonoesters. The most marked effect of land use was a decrease in PME activity under recent pastures, indicating an increase of PME stability in topsoils after the maize-grass ley plantation. The importance of the pH of the PME activity measurement is also discussed. Key Words: Organic P, labile P, 31 P-NMR, phosphosmonoesterase, Cerrado, Oxisols
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
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Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it