Visuelle Beobachtung der Auflösung und Wiederablagerung von Palladium während der Suzuki‐Miyaura‐Reaktion
Bibliographic record
Abstract
Eben war es noch da …︁: Mithilfe eines Miniaturreaktors, in dem ein kleiner Teil einer Palladiumfolie gezielt erhitzt werden kann, wurden die Veränderungen der Katalysatoroberfläche während der Suzuki-Miyaura-Kupplung beobachtet. Das Pd löste sich nur in der erhitzten Zone und nur in Gegenwart von Aryliodid auf, während die Ablagerung von Pd vorzugsweise in unmittelbarer Nähe der erhitzten Zone stattfand. SEM- und XPS-Untersuchungen liefern Informationen über den Zustand der Pd-Oberfläche vor und nach der Reaktion.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.002 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.003 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".