Fick's law of diffusion depth profiles applied to the degradation of oxidized polystyrene during ARXPS analysis
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Bibliographic record
Abstract
Abstract Angle‐resolved x‐ray photoelectron spectroscopy (ARXPS) measurements were made, using Al Kα and Mg Kα radiation alternately, on a polystyrene sample that had been exposed to a helium plasma. It was observed that oxygen was introduced into the sample surface by the plasma treatment, and that some of it was lost over a period of 5 h under x‐ray irradiation in the vacuum of the spectrometer. Laplace transforms of Fick's law of diffusion profiles were derived and applied to the data. The ARXPS results obtained in this study are consistent with a sample history in which the oxidation of the polymer surface resulting from exposure to plasma is controlled by a diffusion process, whereas the loss of oxygen during exposure to x‐rays is principally controlled by a first‐order reaction such as the liberation of oxygen (presumably as CO 2 ) from carbon–oxygen groups by the action of radicals created by the ionizing radiation. Copyright © 2005 John Wiley & Sons, Ltd.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.002 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
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Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
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