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Record W2014495743 · doi:10.1002/cjce.20514

Miniemulsions using static mixers: Part 2. Co‐emulsification and composite materials using SMX static mixers

2011· article· en· W2014495743 on OpenAlexvenueno aff
Gholamali Farzi, Élodie Bourgeat‐Lami, Timothy F. L. McKenna

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2011
Typearticle
Languageen
FieldChemistry
TopicAdvanced Polymer Synthesis and Characterization
Canadian institutionsnot available
Fundersnot available
KeywordsMiniemulsionMonomerStatic mixerEmulsionMaterials scienceAcrylateChemical engineeringComposite numberButyl acrylatePolymer chemistryComposite materialPolymer

Abstract

fetched live from OpenAlex

Abstract A 50:50 mixture of methylmethacrylate (MMA) and butyl acrylate was emulsified, then polymerised using different static mixers. It was shown that the emulsification behaviour was very different from that observed for MMA alone under similar conditions. It was shown that the hydrophobicity of the monomers had a strong influence on the droplet size and stability. It was also shown that the amount of work done on the emulsion is important for obtaining polymerisable droplets, and that monomer systems that are difficult to miniemulsify with a low energy system can in fact be made to form stable emulsions simply by changing the emulsification conditions. Finally, it was shown that when the miniemulsification conditions are correctly chosen, it is possible to generate miniemulsion dispersions containing silica that can be successfully polymerised to produce silica/polyacrylic nanocomposites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.523

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.036
GPT teacher head0.227
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2011
Admission routes1
Has abstractyes

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