Cross-conjugated <i>Z</i>- and <i>E</i>-3-ferrocenylmethyl-idene-4-methyl-2-phenylpenta-1,4-dienes — Synthesis and some chemical properties
Bibliographic record
Abstract
Dehydration of (Z)- and (E)-4-ferrocenyl-3-isopropenyl-2-phenylbut-3-en-2-ols and Z-3-ferrocenyl methyl idene-4-methyl-2-phenylpentane-2,4-diol affords (Z)- and (E)-3-ferrocenylethylidene-4-methyl-2-phenylpenta-1,4-dienes with a system of three cross-conjugated double bonds. One of the methylidene groups of the trienes obtained is smoothly protonated under the action of tetrafluoroboric acid etherate to yield (Z)- and (E)-3-ferrocenyl-2-isopropenyl-1-methyl-1-phenylallyl tetrafluoroborates. The cross-conjugated trienes undergo cationic cycloaddition to these allylic cations as well as proton-induced cyclodimerization resulting in 7-ferrocenyl-4-ferrocenylmethylidene-1,3-dimethyl-5-phenyl-8-(1-phenylethylidene)bicyclo[3.3.1]non-2-ene and isomeric 1,5-diferrocenyl-2,6-diisopropenyl-3,7-diphenylocta-1,3,6-trienes.Key words: cross-conjugated trienes, ferrocenylallylic cations, cyclodimerization, cycloaddition, ferrocene.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".