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Record W2017261148 · doi:10.1139/v02-036

Utilisation de vecteurs tournants pour l'optimisation de la formulation de mélanges de solvants

2002· article· en· W2017261148 on OpenAlexvenueno aff
Serge Alex

Bibliographic record

VenueCanadian Journal of Chemistry · 2002
Typearticle
Languageen
FieldEngineering
TopicProcess Optimization and Integration
Canadian institutionsnot available
Fundersnot available
KeywordsChemistrySolventDegreasingRepresentation (politics)Process engineeringBiological systemOrganic chemistry

Abstract

fetched live from OpenAlex

A new strategy is proposed to optimize the design of solvent blends without using complex mathematical models and (or) graphical representations. All calculations are made with standard electronic programs, such as Excel, Lotus, etc. This approach was developed for the cleaning and degreasing industry, which has to find new recipes of solvent blends on a regular basis. The process relies on a visual analysis of the sum of normalized rotating vectors associated with the chemical composition and the physical properties of the individual components. This approach allows for representation of all parameters on a two-dimensional plot, including information about chemical composition, as well as the physical properties to be optimized. The research of a new mixture of halogenated solvents will be used as an example to illustrate the various steps of this technique. This method is not limited to solvent applications; it also applies to all problems that involve comparisons of physical and chemical properties of blends.Key words: solvents, mixtures, components, optimization, cleaning.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.003
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.005
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.003
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.209
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2002
Admission routes1
Has abstractyes

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