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Record W2019633940 · doi:10.1021/ma011163q

Swelling of Poly(<scp>dl</scp>-lactide) and Polylactide-<i>co</i>-glycolide in Humid Environments

2001· article· en· W2019633940 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMacromolecules · 2001
Typearticle
Languageen
FieldEngineering
TopicAcoustic Wave Resonator Technologies
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsSwellingQuartz crystal microbalancePolymerPolymer chemistryCopolymerKineticsChemical engineeringChemistryRelative humidityWater vaporAdsorptionLactideMaterials scienceThermodynamicsOrganic chemistryComposite material

Abstract

fetched live from OpenAlex

The water uptake of poly( dl -lactide) (PLA) and its copolymer with glycolic acid (PLGA 50:50) has been studied using a quartz crystal microbalance (QCM). The polymers were swollen in humid atmospheres at 20 °C in order to probe both the kinetics of adsorption and the equilibrium amount of water taken up at low concentrations. The relative humidity of the air was controlled using saturated salt solutions. By equating the chemical potentials of the water vapor and the polymer/water mixture at equilibrium, it was possible to extract the Flory−Huggins interaction parameter χ from a simple binary mixing theory. Studies were also performed on the formulations of these materials with a model polypeptide active ingredient. The kinetics of swelling were described using a model based on the Thomas−Windle model of penetrant diffusion in glassy polymers.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.030
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.211
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it