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Effect of electrolyte additives on microstructure and properties of electroplated chromium coatings

2011· article· en· W2019787419 on OpenAlexafffund
Igor Makarov, J Chen, E Yurasovskaya, John McCracken, H. Henein

Bibliographic record

VenueCanadian Metallurgical Quarterly · 2011
Typearticle
Languageen
FieldMaterials Science
TopicCorrosion Behavior and Inhibition
Canadian institutionsUniversity of British ColumbiaUniversity of AlbertaAlberta Environment and Protected Areas
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsElectroplatingCathodeMicrostructureChromiumElectrolyteMaterials sciencePlating (geology)Chrome platingMetallurgyHexavalent chromiumCathodic protectionCurrent densityChemical engineeringComposite materialAnodeElectrodeChemistryLayer (electronics)

Abstract

fetched live from OpenAlex

Recent progress in environmental science provides an incentive to explore the use of hexavalent chromium for anticorrosion and wear protection purposes. To this end, this work aims to explore the evolution of the microstructure of chromium coatings as a function of electric current through the electrolyte in the presence of organic and non-organic additives. In this study, the fundamental properties of electroplating related to hard chromium such as hardness (wear resistance) and cathode efficiency are reviewed with respect to cathode current. The results obtained show that the microstructure is sensitive to the presence of organic admixtures in the plating solution. In addition, the effect of hard microparticles on the plating process at enhanced values of cathode current is reported. The cathode efficiency for different plating speeds and in different chromium electrolytes is calculated from the experimental results.Les progrès récents des sciences de l’environnement fournissent une incitation à explorer l’utilisation du chrome hexavalent pour le but de protection contre la corrosion et l’usure. À cette fin, ce travail vise à explorer l’évolution de la microstructure de revêtements de chrome en fonction du courant électrique à travers l’électrolyte en présence d’additifs organiques et inorganiques. Dans cette étude, on analyse les propriétés fondamentales de l’électroplastie reliées au chrome dur comme la dureté (résistance à l’usure) et l’efficacité de la cathode, par rapport au courant de la cathode. Les résultats obtenus montrent que la microstructure est sensible à la présence d’additifs organiques dans la solution de placage. En plus, on rapporte l’effet de micro particules dures sur le procédé de placage à des valeurs augmentées du courant de la cathode. À partir des résultats expérimentaux, on calcule l’efficacité de la cathode à différentes vitesses de placage et avec différents électrolytes de chrome.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.201
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2011
Admission routes2
Has abstractyes

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