Kinetics and products study of the reaction of BrO radicals with gaseous mercury
Why this work is in the frame
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Bibliographic record
Abstract
Broreactions of elemental mercury was as a major candidate for near complete depletion of elemental mercury in polar region. The kinetics of the reaction between BrO radicals with gaseous mercury was identified using relative rate method by Gas Chromatography with Mass spectroscopic Detection (GC-MS) at room temperature (298 ± I K) and at atmospheric pressure 760 ± Torr in the N 2 diluent. Propane, DMS and butane were used as reference molecules. The upper and lower limits rate constant for reaction of Hg° with BrO was estimated to be 1.0 × 10 -13 and 1.0 x 10 -15 cm 3 molecules -1 s -1 , respectively. BrO radicals were produced from the photolysis of bromine and dibromomethane in presence of ozone and detected by MS at m / e = 95 or 97. Ozone was produced in a Silent discharged generator. Reaction products were identified using direct mass spectrometer with chemical ionization ion source.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it