Origins of Displacement in 1-Adamantanethiolate Self-Assembled Monolayers
Bibliographic record
Abstract
We have investigated the origins of the susceptibility of 1-adamantanethiolate self-assembled monolayers on Au{111} to displacement by other thiol molecules. Using scanning tunneling microscopy, X-ray photoelectron spectroscopy, and electrochemical desportion experiments to probe separated self-assembled monolayers on Au{111} created by the displacement of 1-adamantanethiolate with n -dodecanethiolate, we have shown that there is no difference between the chemical environments at the Au{111} surface for single-component or separated self-assembled monolayers of each molecule. There are, however, differences in interaction strengths between the 1-adamantanethiolate molecules and the n -dodecanethiolate molecules that contribute to 1-adamantanethiolate displacement.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".