Periodic Mesoporous Silica-Supported Recyclable Rhodium-Complexed Dendrimer Catalysts
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Polyamidoamine (PAMAM) dendrimers up to the third generation were grown for the first time inside the channels of a large-pore (6.5 nm) MCM-41 silica. In-depth characterization of such materials showed that the dendrimers grew inside the channels. The third generation was found to almost completely fill the pore system. The supported dendrimers of generations 0, 1, and 2 were phosphinomethylated and then complexed with rhodium. The G(0) and G(1) materials were found to be very active in olefin hydroformylation. The hydroformylation of 1-octene was accomplished with a turnover frequency of 1800 h - 1 at 70 °C and the catalyst could be recycled several times without loss in activity.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.010 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it