TiO <sub>2</sub> /biscyanine and CdS/biscyanine heterostructures — Influence of the structural composition on the photocatalytic activity
Bibliographic record
Abstract
This paper deals with investigation of a character of the light reflection and absorption of some newly synthesized heterostructural materials based on TiO 2 or CdS semiconductors and bisquinocyanine dyes (carbocyanine and styrile). Changes in spectral parameters of the heterostructures caused by adding the dye to the semiconducting material have also been investigated. The changes in the spectra can be caused by different chromophores disposition induced by influence of the semiconductor on the electron configuration in the dye molecules. A well-known test reaction of methylene blue reduction has been used to detect the photocatalytic activity of the materials, which was found directly depending on the efficiency of the mutual influence of the components of the heterostructures. The heterostructures containing a dye, which causes more significant spectral changes, ensure higher photocatalytic activity.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".