VAPOR-PHASE CHEMICAL FUNCTIONALIZATION OF HIGH POROSITY, NANOSTRUCTURED THIN FILMS
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Bibliographic record
Abstract
Trifluoropropyl-trichlorosilane reagents were used to tailor the surface chemistry of porous nano-structured thin films fabricated using glancing angle deposition (GLAD). GLAD produces high surface area films of isolated columnar structures and provides complete control over the film morphology. Here, the chemical tunability of these GLAD films was investigated using solution and vapor-phase surface functionalization methods. All films were characterized using scanning electron microscopy, X-ray photoelectron spectroscopy and advancing aqueous contact angle measurements. Our results indicate that the surface chemistry of the GLAD films was effectively changed after functionalization by either approaches. We also note that vapor-phase functionalization provides more consistent results and eliminates the need for organic solvents, making it an ideal method for tailoring the surface properties of GLAD films for specific applications.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it