Synthesis, characterization, and optical properties of a novel azo-dye bearing an oligo(ethylene glycol) methyl ether side chain in solution and in the solid state
Bibliographic record
Abstract
A novel azobenzene compound bearing a short poly(ethylene glycol) methyl ether side chain, N-methyl-N-{4-[(E)-(4-nitrophenyl)diazenyl]phenyl}-N-(3,6,9,12,15,18,21,24-octaoxapentacos-1-yl)amine (RED-PEGM-8) was synthesized and characterized. RED-PEGM-8 exhibits a thermal behavior similar to that of Disperse Red-1; however, its thermal stability, as well as its T g and T m values, are lower because of the presence of the PEGM segment. The optical properties of this compound in solution and in the solid state were studied by UVvis spectroscopy. The appearance of a blue-shifted band in aqueous solutions at high concentrations of the chromophore reveals the existence of H-type aggregates, resulting from ππ intermolecular interactions between the azobenzene units. Strong intermolecular interactions were also confirmed by 1 H NMR measurements. Optical properties of RED-PEGM-8 in the solid state (thin film) also suggest the presence of H aggregates. However, a tail is also detected in the red region of the absorption spectrum, which could be because of the formation of J-type aggregates in the thin film.Key words: aggregation, azo-dye, poly(ethylene glycol) methyl ether.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".