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Record W2021506159 · doi:10.1021/cm011513n

Electroforming of Copper Structures at Nanometer-Sized Gaps of Self-assembled Monolayers on Silver

2002· article· en· W2021506159 on OpenAlexfundno aff
Hong Yang, J. Christopher Love, Francisco Javier Arias, George M. Whitesides

Bibliographic record

VenueChemistry of Materials · 2002
Typearticle
Languageen
FieldEngineering
TopicMolecular Junctions and Nanostructures
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaDefense Advanced Research Projects Agency
KeywordsCopperMaterials scienceNanometreMonolayerPolarizerNanostructureElectroformingNanotechnologyOptoelectronicsAnti-reflective coatingMetalOpticsComposite materialCoatingLayer (electronics)Metallurgy

Abstract

fetched live from OpenAlex

This paper describes a method to fabricate micro- and nanostructures of copper by electrodeposition onto nanometer-sized gaps in self-assembled monolayers (SAM) of alkanethiolates on metal surfaces. We have demonstrated that the approach can produce large numbers of metallic micro- or nanostructures over large (2 cm 2 ) areas with features as small as ≈70 nm. The electrodeposited copper structures can be transferred using Scotch tape onto both flat and curved substrates. Linear arrays of copper structures have been tested for use as optical polarizers. A polarization ratio R = ≈2.0 was found for light with λ = 633 nm in transmission mode for linear arrays of copper wires (≈220 nm, with a 1-μm pitch) mounted on antireflective windows.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.189
Teacher spread0.183 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations21
Published2002
Admission routes1
Has abstractyes

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