A Study of the Adsorption and Thermal Behavior of (η<sup>6</sup>-C<sub>6</sub>H<sub>6</sub>)Cr(CO)<sub>3</sub> in Zeolite Y by Vibrational Spectroscopy
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Bibliographic record
Abstract
The adsorption and thermal behavior of (η 6 -benzene)tricarbonylchromium(0), (η 6 -C 6 H 6 )Cr(CO) 3, inside zeolite Y have been investigated under different conditions by the FT-Raman technique in conjunction with FT-IR spectroscopy. The thermal decomposition of (η 6 -C 6 H 6 )Cr(CO) 3 in zeolite Y seems strongly dependent on the experimental conditions employed: heating (η 6 -C 6 H 6 )Cr(CO) 3 adsorbed inside zeolite Y in a Schlenk tube under nitrogen flow results in the formation of benzene and Cr metal, whereas heating the same complex in a closed vessel yields a different metal carbonyl species, Cr(CO) 6 . The thermal behavior observed in the present study is different from that reported previously in the literature.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it