New Approach to Rapid Generation and Screening of Diverse Catalytic Materials on Electrode Surfaces
Bibliographic record
Abstract
This paper describes a general approach to rapid generation and screening of catalytic materials on electrode surfaces. The properties of the corresponding polymers, including catalytic performance, can be modulated by varying the monomer feed ratios, monomer concentrations, and applied polymerization potential. Thus, the generation of the polymeric TEMPO (2,2,6,6-tetramethylpiperidin-1-yloxy) catalysts was performed by electrochemical copolymerization of 2,2‘-bithiophene with the TEMPO catalyst precursors containing pyrrole side chains. A library of catalyst films was obtained over a wide range of bithiophene/pyrrole ratios upon repeated scanning of the applied potential from +0.5 to +1.4 V (vs Ag/AgCl). The resulting catalyst films were utilized in both chemical and electrochemical oxidation of primary alcohols to aldehydes.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".