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Record W2023519395 · doi:10.1149/1.2405869

Dielectric Properties and Ionic Conductivity of Anodic Oxide Films on Tantalum

2007· article· en· W2023519395 on OpenAlexafffund
L. Young, A. Kulpa

Bibliographic record

VenueJournal of The Electrochemical Society · 2007
Typearticle
Languageen
FieldMaterials Science
TopicAnodic Oxide Films and Nanostructures
Canadian institutionsUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of British Columbia
KeywordsIonic bondingDielectricPolarization (electrochemistry)Current (fluid)TantalumAnodeIonic conductivityMaterials scienceOxideChemical physicsAnalytical Chemistry (journal)Condensed matter physicsChemistryIonOptoelectronicsThermodynamicsElectrodePhysicsMetallurgyPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

We have investigated certain aspects of the dielectric properties of anodic oxide films on tantalum in connection with Dignam's theory that a special current-driven polarization process is responsible for the transients shown by the ionic current on changing the electric field in the oxide. In his experiments, which were claimed to prove this theory, films were first held at potentials giving fields too low to produce significant ionic current. When voltage pulses were applied large enough to produce fields giving ionic current, extra current was observed to flow for a short time. This was taken as due to the decay of the dielectric polarization built up due to the ionic current, and partial numerical agreement with the model was found. In the present experiments the discharge current flowing after longer periods of voltage application or of ionic current flow was investigated with the aim of finding if more polarization was indeed produced by ionic current flow. The current was not found to be larger after discharge from fields giving ionic current, as required by Dignam's model. It is argued that structural changes in the glassy oxide are responsible for the transients.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.221
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2007
Admission routes2
Has abstractyes

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Same venueJournal of The Electrochemical SocietySame topicAnodic Oxide Films and NanostructuresFrench-language works237,207