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Record W2024447833 · doi:10.1021/je9003228

Experimental Investigation of Methane Hydrates Equilibrium Condition in the Presence of KNO<sub>3</sub>, MgSO<sub>4</sub>, and CuSO<sub>4</sub>

2009· article· en· W2024447833 on OpenAlexaff
Lutz O. Porz, Matthew A. Clarke, Lothar R. Oellrich

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2009
Typearticle
Languageen
FieldEnvironmental Science
TopicMethane Hydrates and Related Phenomena
Canadian institutionsUniversity of Calgary
Fundersnot available
KeywordsChemistryIsochoric processHydrateMethaneClathrate hydrateMass fractionAqueous solutionSalt (chemistry)Inorganic chemistryThermodynamic equilibriumFraction (chemistry)ThermodynamicsPhysical chemistryChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

A new isochoric reactor was commissioned for studying gas hydrate equilibrium formation, and experiments were carried out to measure the equilibrium conditions for methane hydrate formation in aqueous solutions of CuSO 4, KNO 3, and MgSO 4 . The experimental conditions ranged from (273 to 281) K in temperature and between (3 and 6) MPa in pressure, and the mass fraction of salt ranged from (0.025 to 0.402), depending on the salt. In the case of all three salts, it was observed that there was an inhibiting effect on the hydrate formation, which is in contrast to a previous observation that found CuSO 4 had a promoting effect on CO 2 hydrates.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.842

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.235
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2009
Admission routes1
Has abstractyes

Explore more

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