Effect of high field on dielectric relaxation properties of polycarbonate
Bibliographic record
Abstract
It is known that glassy state is a non-equilibrium state. Due to the energy excess, resulting from kinetic conditions during cooling from the liquid state, all glasses and especially polymers sustain a phenomenon called physical ageing or structural relaxation under the glass transition temperature. This phenomenon results in decrease with time of physical properties due to rearrangements of macromolecules in order to decrease their energy. This decrease directly affects the durability of polymers and molecules movements are associated with glass transition dynamics. But, the interaction between macromolecules movements induced by physical ageing and by electrical field is not known. In order to clarify this interaction, a model thermoplastic, polycarbonate, has been studied with dielectric spectroscopy under different high-field AC conditions up to 700V/mm. Dielectric spectroscopy technique has been chosen because it allows simultaneously to apply an electrical field and to follow the molecular dynamics by controlling the temperature.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".