CATALYTIC DEHYDROCOUPLING OF AMINE-BORANE ADDUCTS TO FORM AMINOBORANES AND BORAZINES
Bibliographic record
Abstract
A mild, catalytic dehydrocoupling route to aminoboranes and borazine derivatives from either primary or secondary amine-borane adducts has been developed using late transition metal complexes as precatalysts. The dehydrocoupling of Me 2 NH·BH 3 was found to be catalyzed by 0.5 mol% [Rh(1,5-cod)(μ-Cl)] 2 in solution at 25°C to give [Me 2 N─BH 2 ] 2 (1) quantitatively after ca. 8 h. This new catalytic method was extended to other secondary adducts RR ′NH·BH 3 which afforded the dimeric [(1,4-C 4 H 8 )N─BH 2 ] 2 (2) and [PhCH 2 (Me)N─BH 2 ] 2 (3) or the monomeric aminoborane i Pr 2 N═BH 2 (4) under mild conditions. The catalytic dehydrocoupling of NH 3 ·BH 3 , MeNH 2 ·BH 3 , and PhNH 2 ·BH 3 at 45°C affords the borazine derivatives [RN─BH] 3 (5: R = H; 6: R = Me; 7:R = Ph). TEM analysis of the contents of the reaction solution for the [Rh(1,5-cod)(μ-Cl)] 2 catalyzed dehydrocoupling of Me 2 NH·BH 3 together with Hg poisoning experiments suggested a soluble heterogeneous catalyst involving Rh(0) nanoclusters.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".