Enantiopure <i>C</i><sub>1</sub>-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation
Why is this work in the frame?
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
No Canadian affiliation. An affiliation-only frame — the usual design — would never have seen this work. It is one of the works that make the case for inverting the frame.
Machine scores (provisional)
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
- Teacher spread
- 0.238 · how far apart the two teachers sit on this one work
- Validation status
score_only:v0-immature-baseline· verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it
Abstract
Enantiopure C(1)-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
The record
- Venue
- Journal of the American Chemical Society
- Topic
- Asymmetric Hydrogenation and Catalysis
- Field
- Chemistry
- Canadian institutions
- —
- Funders
- Natural Sciences and Engineering Research Council of CanadaUS-UK Fulbright CommissionDeutsche ForschungsgemeinschaftAstraZenecaNational Science Foundation
- Keywords
- Enantiopure drugChemistryGeminalAlkeneCobaltPyridineEnantioselective synthesisCatalysisHydrideMedicinal chemistryOrganic chemistryHydrogen
- Has abstract in OpenAlex
- yes