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Record W2026781011 · doi:10.1002/anie.200905811

Cover Picture: Templated Ligand Environments for the Selective Incorporation of Different Metals into DNA (Angew. Chem. Int. Ed. 52/2009)

2009· paratext· en· W2026781011 on OpenAlexaff
Hua Yang, Andrzej Z. Rys, Christopher K. McLaughlin, Hanadi F. Sleiman

Bibliographic record

VenueAngewandte Chemie International Edition · 2009
Typeparatext
Languageen
FieldMedicine
TopicMetal complexes synthesis and properties
Canadian institutionsMcGill University
Fundersnot available
KeywordsLigand (biochemistry)MetalDNACover (algebra)RedoxChemistryMaterials scienceNanotechnologyCombinatorial chemistryInorganic chemistryBiochemistryEngineeringOrganic chemistryReceptor

Abstract

fetched live from OpenAlex

DNA can template the formation of different ligand environments that are selective for their binding metals. H. F. Sleiman and co-workers describe in their Communication on page 9919 ff. how placement of a metal in the incorrect DNA-templated environment results in the occurrence of “error-checking”: the metal can spontaneously adjust its redox state, displace another labile metal to form a more-stable complex, or reorganize the coordination site to create a more-favored complex.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.607
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.278
Teacher spread0.251 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2009
Admission routes1
Has abstractyes

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