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Record W2027524707 · doi:10.1021/ja056838+

Self-Trapping of Spatially and Temporally Incoherent White Light in a Photochemical Medium

2005· article· en· W2027524707 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of the American Chemical Society · 2005
Typearticle
Languageen
FieldPhysics and Astronomy
TopicNonlinear Photonic Systems
Canadian institutionsMcMaster University
FundersMcMaster University
KeywordsChemistryFemtosecondRefractive indexPolymerizationOpticsBeam (structure)DiffractionLaserPolymerPhysics

Abstract

fetched live from OpenAlex

We report that a beam of spatially and temporally incoherent white light self-traps by initiating free-radical polymerization in an organosiloxane medium. Refractive index changes due to polymerization lead to the formation of a narrow channel waveguide that traps and guides the entire multimode, broadband beam without diffraction. The response time of the system, which is determined by the inherently slow rate of free-radical polymerization, exceeds by several orders of magnitude the femtosecond-scale random phase fluctuations that characterize white light. Self-trapping of incoherent light is possible in the photochemical medium because it responds to the time-averaged intensity profile of the white light beam.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.146
Threshold uncertainty score0.356

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.235
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it