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Record W2028500204 · doi:10.1039/c4qi00209a

Reconciling order, stability, and porosity in phosphonate metal–organic frameworks via HF-mediated synthesis

2015· article· en· W2028500204 on OpenAlexafffund
Roger K. Mah, Benjamin S. Gelfand, Jared M. Taylor, George K. H. Shimizu

Bibliographic record

VenueInorganic Chemistry Frontiers · 2015
Typearticle
Languageen
FieldChemistry
TopicMetal-Organic Frameworks: Synthesis and Applications
Canadian institutionsAlberta Bible CollegeUniversity of Calgary
FundersCarbon Management CanadaAlberta Innovates - Technology Futures
KeywordsPhosphonatePorosityMaterials scienceMetal-organic frameworkOrder (exchange)Chemical engineeringMetalChemistryOrganic chemistryMetallurgyComposite materialBusinessAdsorptionEngineering

Abstract

fetched live from OpenAlex

We report the use of an HF-mediated synthesis to control porosity and order in robust Zr phosphonate frameworks.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.013
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0060.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.216
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations22
Published2015
Admission routes2
Has abstractyes

Explore more

Same venueInorganic Chemistry FrontiersSame topicMetal-Organic Frameworks: Synthesis and ApplicationsFrench-language works237,207