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Record W2029534411 · doi:10.1021/ie060287u

Investigating the Application of Enzyme Carbonic Anhydrase for CO<sub>2</sub> Sequestration Purposes

2007· article· en· W2029534411 on OpenAlexafffund
Parissa Mirjafari, K. Asghari, Nader Mahinpey

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2007
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicEnzyme function and inhibition
Canadian institutionsUniversity of Regina
FundersUniversity of Regina
KeywordsCarbonic anhydraseChemistryCalcium carbonateCarbon dioxideCarbonatePrecipitationInorganic chemistryCalciumCarbonate mineralsEnzymeOrganic chemistry

Abstract

fetched live from OpenAlex

Biological sequestration of carbon dioxide (CO 2 ) in geological formations is one of the proposed methods to reduce the carbon dioxide released into the atmosphere. In this method, an enzyme is used to enhance the hydration and subsequent precipitation of CO 2 . In the present work, the effect of bovine carbonic anhydrase on the hydration of CO 2, and its precipitation in the form of calcium carbonate, was studied. The enzyme enhanced the hydration reaction. The rate of hydration reaction increased with both the enzyme concentration and temperature. The precipitation of calcium carbonate was promoted in the presence of the enzyme. The concentration of the enzyme did not affect the precipitation; however, temperature impacted the precipitation of calcium carbonate. At higher temperatures, less calcium carbonate was formed. Also, in the presence of the enzyme, calcium carbonate settled more quickly. The enzyme activity was not influenced by the pH of the reaction mixture. In contrast, the formation of calcium carbonate was affected by the pH of the solution. A kinetic analysis was performed for the bovine carbonic anhydrase. Based on the experimental results, the activation energy and catalytic rate constant are estimated as 700.91 cal/mol and 0.65 s -1, respectively.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.057
GPT teacher head0.331
Teacher spread0.275 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations305
Published2007
Admission routes2
Has abstractyes

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