Functional Star Polymers with a Cholic Acid Core and their Thermosensitive Properties
Bibliographic record
Abstract
Star polymers derived from cholic acid with poly(allyl glycidyl ether) arms have been prepared via anionic polymerization, yielding polymers with well-defined molecular weight and low polydispersity. The double bonds of the allyl groups on the polymer are used to introduce either amine or carboxylic acid groups to obtain amphiphilic polymers with cationic and anionic groups, respectively. The polymers can aggregate in water above a certain critical concentration, which was found to vary with the arm length of the star polymers. The star polymers bearing amino groups showed interesting thermosensitivity, which also depends on the pH of the media. A simple acetylation of the amine groups can sharpen the transition and vary the cloud point from 15 to 48 degrees C, depending on the degree of acetylation. Such polymers offer useful alternatives to the existing thermosensitive polymers.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".