Preparation of Azobenzene-Containing Amphiphilic Diblock Copolymers for Light-Responsive Micellar Aggregates
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Diblock copolymers composed of a side-chain liquid crystalline azobenzene-containing polymethacrylate and poly( tert -butyl acrylate) (PAzoMA- b -P t BA) were prepared using atom-transfer radical polymerization (ATRP). After subsequent selective hydrolysis of P t BA yielding poly(acrylic acid) (PAA), amphiphilic diblock copolymers of PAzoMA- b -PAA were obtained. Aggregation of either PAzoMA or PAA block occurs in solvents selective for one of the blocks. Adding water into dioxane solution of PAzoMA- b -PAA forms micellar aggregates due to the hydrophobic PAzoMA block. Under alternating UV and visible light illumination, reversible changes in micellar aggregates, for both core−shell micelles and vesicles, took place as a result of the reversible trans−cis photoisomerization of azobenzene mesogens in PAzoMA.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it