Participation in Self-Emulsification by Oil-Thin Film Voltammetry
Bibliographic record
Abstract
When an oil phase comes in contact with an aqueous phase, emulsions are formed spontaneously in each phase even without surfactant. The self-emulsification seems inconsistent with the electron transfer model proposed by Anson, in which ferricyanide in the aqueous phase is reduced at the oil/water interface by decamethylferrocene of the thin nitrobenzene phase. Anson’s experimental data were here reproduced at slow scan voltammetry. However, the electron transfer model did not agree with our experimental results at high scan rates, in that the reduction wave of ferricyanide appeared without decamethylferrocene. Ferricyanide was demonstrated to pass through the nitrobenzene film in the form of aqueous droplets, which were adsorbed on the electrode surface. Formation of aqueous droplets can explain electrode reactions at carbon paste electrodes without including redox species in paste.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".