Emergence of Superconductivity, Valence Bond Order, and Mott Insulators in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>Pd</mml:mi><mml:mo stretchy="false">[</mml:mo><mml:mo stretchy="false">(</mml:mo><mml:mi>dmit</mml:mi><mml:msub><mml:mo stretchy="false">)</mml:mo><mml:mn>2</mml:mn></mml:msub><mml:mo stretchy="false">]</mml:mo></mml:math>Based Organic Salts
Bibliographic record
Abstract
The EtMe(3)P and EtMe(3)Sb triangular organic salts are distinguished from other Pd[(dmit)(2)] based salts, as they display valence bond and no long-range order, respectively. Under pressure, a superconducting phase is revealed in EtMe(3)P near the boundary of valence bond order. We use slave-rotor theory with an enlarged unit cell to study competition between uniform and broken translational symmetry states, offering a theoretical framework capturing the superconducting, valence bond order, spin liquid, and metallic phases on an isotropic triangular lattice. Our finite temperature phase diagram manifests a remarkable resemblance to the phase diagram of the EtMe(3)P salt, where the reentrant transition of insulator-metal-insulator type can be explained by an entropy difference between the metal and U(1) spin liquid. We predict different temperature dependence of the specific heat between the spin liquid and metal.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.005 | 0.005 |
| Meta-epidemiology (narrow) | 0.003 | 0.004 |
| Meta-epidemiology (broad) | 0.002 | 0.003 |
| Bibliometrics | 0.001 | 0.004 |
| Science and technology studies | 0.002 | 0.005 |
| Scholarly communication | 0.002 | 0.004 |
| Open science | 0.006 | 0.005 |
| Research integrity | 0.003 | 0.004 |
| Insufficient payload (model declined to judge) | 0.011 | 0.003 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".