Relaxation processes in aromatic polyimide
Bibliographic record
Abstract
Electrical conduction in non-conjugated insulating polymers such as Kapton(R) films was studied as a function of temperature, T (15–500 K) and electric field F (⩽16 kV cm−1). The time dependent isothermal transient currents (ITC) were also studied at different temperatures (15 K<T<500 K). Thermally stimulated discharge current (TSDC) studies were carried out as a function of initial poling conditions. A distinct change in conduction mechanism as a function of T was observed at T⩾300 K from DC conductivity, ITC and TSDC measurements. The origin of this behaviour is discussed in terms of transition of dipolar at low T to space charge mechanism at high T which can be attributed to carrier trapping and release of charge carriers from the trap states. The effective barrier energy, Δ, for transport and hopping parameter λ(T) are estimated for Kapton on the basis of these studies. The results obtained for Kapton suggest that, for T<Tg at low or moderate fields, the transient currents are essentially governed by dipolar relaxation mechanisms.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".