The Development of Pseudocapacitive Molybdenum Oxynitride Electrodes for Supercapacitors
Why this work is in the frame
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Bibliographic record
Abstract
Mo oxynitride was developed as pseudocapacitive electrode material for supercapacitors. A thin film Mo oxynitride was produced by first electrodeposition of Mo oxide on a Ti substrate followed by a low-temperature (400 o C) heat treatment in N 2 environment. XPS analyses showed that the surface of the Mo oxynitride film was composed of a mixture of MoO 3 , MoO 2 and less than 20 at.% Mo 2 N. However, the electrochemical behavior of the Mo oxynitride film was significantly different from that of Mo oxide but much similar to the behavior of pure Mo 2 N, a known pseudocapacitive material. The cycle life and stability of the Mo oxynitride were much improved over the Mo oxide. A two-electrode symmetric cell using the developed Mo oxynitride electrodes was demonstrated and showed high rate performance. An asymmetric cell using a Mo oxynitride as negative electrode and a carbon as positive electrode was also established and showed an extended voltage window and, thus, an increased energy density.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it