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Record W2033438156 · doi:10.1002/masy.200951104

A Study of Particle‐Surface Interactions During Olefin Polymerisation in Gas Phase Reactors

2009· article· en· W2033438156 on OpenAlexaff
Erik J. G. Eriksson, Timothy F. L. McKenna

Bibliographic record

VenueMacromolecular Symposia · 2009
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsQueen's University
Fundersnot available
KeywordsMaterials sciencePolymerParticle (ecology)PolymerizationWork (physics)Heat transferHeat exchangerPhase (matter)Composite materialChemical engineeringMechanicsChemistryMechanical engineeringOrganic chemistryEngineering

Abstract

fetched live from OpenAlex

Abstract This work focuses on the heat exchange between a polymer particle and the reactor wall, especially for cases with low gas velocity. The role of different wall materials (or heat transfer conditions) is investigated with an eye to understanding how this influences the likelihood of particle melting, and, indirectly, wall sheeting. The main focus of this work was to simulate the temperature profiles inside growing polymer particles in the vicinity of the reactor wall when it is clean (steel) or covered with a layer of non reactive polymer. As a comparison, we have also simulated the reactor wall as being glass to represent bench scale polymerization equipment. The results from this work can help to understand how for instance wall sheeting can be accelerated if the reactor walls are not clean and how we can compare results from bench scale experiments to industrial scale units.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.146
Threshold uncertainty score0.680

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.252
Teacher spread0.245 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2009
Admission routes1
Has abstractyes

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