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Record W2034472282 · doi:10.1021/cg9004505

Effects of Cocoa Butter Origin, Tempering Procedure, and Structure on Oil Migration Kinetics

2009· article· en· W2034472282 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueCrystal Growth & Design · 2009
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicFood Chemistry and Fat Analysis
Canadian institutionsUniversity of Guelph
FundersNatural Sciences and Engineering Research Council of CanadaOntario Ministry of Food and Agriculture
KeywordsTemperingKineticsChemistryFood scienceAnimal scienceMaterials scienceComposite materialBiology

Abstract

fetched live from OpenAlex

The effects of cocoa butter (CB) origin, tempering procedure, and structure on oil migration kinetics were studied using a flatbed scanner followed by image processing and analysis. The migration rate (OMR) and migration distance ( I 10 ) of stained oil were determined in tempered and nontempered CBs. Tempered matrices had 10 to 50 times lower OMRs than nontempered CBs. In addition, the lag phase observed before significant oil migration was also significantly longer in tempered CBs (12 days vs 2 days in nontempered butters). Moreover, cocoa butter origin had a strong effect on OMR. Brazilian and Nigerian CBs had the highest OMR in both tempered and nontempered samples. Malaysian CB had the third highest OMR, but this effect was only significant in untempered samples. Finally, the lowest OMRs were found in Chinese, Ecuadorian, and Ivorian cocoa butters. The amount of oleic acid and triunsaturated triglycerides (UUU) was strongly correlated to OMR (the higher the UUU concentration, the lower the resistance to oil migration). However, the relationships between the permeability coefficients and structural factors (squared averaged particle size and crystalline domain size) suggest that the micro- and nanostructure of the material also plays a significant role in the oil migration process.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.197

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.194
Teacher spread0.185 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it