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Record W2040943202 · doi:10.1002/zaac.201100275

HfSb<sub>2–<i>x</i></sub>Te<i><sub>x</sub></i>: The Second New Compound on the Quasi‐Binary Section HfSb<sub>2</sub>‐HfTe<sub>2</sub> with Different Sb–Sb Interactions

2011· article· en· W2040943202 on OpenAlexafffund
Katja M. Kleinke, Abdeljalil Assoud, Holger Kleinke

Bibliographic record

VenueZeitschrift für anorganische und allgemeine Chemie · 2011
Typearticle
Languageen
FieldMaterials Science
TopicAdvanced Thermoelectric Materials and Devices
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsAntimonyMonoclinic crystal systemOrthorhombic crystal systemCrystallographyAtom (system on chip)TelluriumGroup (periodic table)Materials scienceMetalChemistryCrystal structureMetallurgy

Abstract

fetched live from OpenAlex

Abstract Thus far, three different ribbons and layers of antimony atoms with various Sb–Sb bonds were found in Hf 5 Sb 9 , HfSb 2 and HfSbTe. We uncovered a new variant when trying to dope Hf 5 Sb 9 with tellurium atoms, namely HfSb 2– x Te x , with 0.4 ≤ x ≤ 0.7. HfSb 2– x Te x adopts the monoclinic OsGe 2 type, space group C 2/ m , a = 10.5216(8) Å, b = 3.7142(3) Å, c = 8.5924(7) Å, β = 11.571(1), V = 292.05(4) Å 3 ( Z = 4) when x = 0.5. This structure is composed of a layer of puckered six‐membered rings of antimony atoms, with Sb–Sb distances of 2.82 and 3.12 Å. The different antimony atom substructures are compared in this article. Independent of the exact Sb/Te ratio, monoclinic HfSb 2– x Te x is predicted to be metallic, as are Hf 5 Sb 9 , HfSb 2 and orthorhombic HfSbTe.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0000.001
Science and technology studies0.0020.001
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.232
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2011
Admission routes2
Has abstractyes

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