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Record W2041312915 · doi:10.1021/jp036138w

Influence of a Nanoscale Gold Thin Layer on Ti/SnO<sub>2</sub>-Sb<sub>2</sub>O<sub>5</sub> Electrodes

2003· article· en· W2041312915 on OpenAlexafffund
Aicheng Chen, Stephanie Nigro

Bibliographic record

VenueThe Journal of Physical Chemistry B · 2003
Typearticle
Languageen
FieldMaterials Science
TopicCatalytic Processes in Materials Science
Canadian institutionsLakehead University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMaterials scienceDielectric spectroscopyElectrodeThin filmCyclic voltammetrySubstrate (aquarium)Layer (electronics)Scanning electron microscopeCoatingSputteringTitaniumElectrochemistryCrystalliteChemical engineeringNanotechnologyAnalytical Chemistry (journal)MetallurgyComposite materialChemistry

Abstract

fetched live from OpenAlex

A nanoscale gold thin film and its influence on Ti/SnO 2 -Sb 2 O 5 coating have been investigated by scanning electron microscopy (SEM) and electrochemical methods such as cyclic voltammetry, electrochemical impedance spectroscopy (EIS), and the chronopotentiometric technique in both acidic and caustic solutions. The gold thin film was fabricated by sputtering, and its thickness was estimated using electrochemical methods. The nanoscale gold thin film on the titanium substrate exhibits electrochemical behavior similar to that of a polycrystalline Au electrode. Our study shows that the presence of a nanoscale Au thin film on the Ti substrate can effectively prevent the growth of a TiO 2 insulating layer between the substrate and the SnO 2 -Sb 2 O 5 coating, resulting either from the thermal procedure during the fabrication of the oxide electrodes or from the electrochemical process during the lifetime tests, thus greatly prolonging the service lifetime of the SnO 2 -Sb 2 O 5 electrodes. The failure mechanisms of the SnO 2 -Sb 2 O 5 electrodes have also been studied using the EIS and SEM techniques.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.233
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations82
Published2003
Admission routes2
Has abstractyes

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Same venueThe Journal of Physical Chemistry BSame topicCatalytic Processes in Materials ScienceFrench-language works237,207