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Record W2041481619 · doi:10.1002/cjce.20439

Three‐parameter cubic equation of state for pure components of heavy oils

2010· article· en· W2041481619 on OpenAlexafffundvenue
Ashutosh Kumar, Amr Henni

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2010
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsPetroleum Technology Research CentreUniversity of Regina
FundersPetroleum Technology Research Centre
KeywordsEquation of stateCubic functionHydrocarbonVapor pressureThermodynamicsCarbon numberChemistryHydrocarbon mixturesVapor–liquid equilibriumConsistency (knowledge bases)AlkaneOrganic chemistryMathematicsPhysicsMathematical analysisAlkyl

Abstract

fetched live from OpenAlex

Abstract A three‐parameter cubic equation of state for pure hydrocarbons is proposed to model PVT properties of heavy hydrocarbons found in heavy oils. Thirty hydrocarbons up to C40 and some commonly found (associated) non‐hydrocarbons in heavy oils have been used to regress the parameters. Predicted results from the proposed equation for the liquid density, vapour pressure, saturated liquid density, and saturated vapour density have been compared with the widely used Peng–Robinson (PR), Soave–Redlich–Kwong (SRK), and Patel and Teja (PT) equations of state. With the increase in carbon number in hydrocarbon, the % average absolute errors in liquid density, vapour pressure, and saturated liquid density prediction using PR, SRK, and PT equations of state were found to increase, whereas the proposed equation shows consistency in the prediction, with a % average absolute error of 2.5% only.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.394
Threshold uncertainty score0.340

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.199
Teacher spread0.185 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2010
Admission routes3
Has abstractyes

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