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Record W2041737073 · doi:10.1139/l09-039

Photocatalytic decolourization of the X3B textile dye in aqueous solutions using iron-rich montmorilloniteA paper submitted to the Journal of Environmental Engineering and Science.

2009· article· en· W2041737073 on OpenAlexvenueno aff
Zongping Wang, Li‐Zhi Huang, Lin Du, Hua Sheng, Bo Lv

Bibliographic record

VenueCanadian Journal of Civil Engineering · 2009
Typearticle
Languageen
FieldEnergy
TopicTiO2 Photocatalysis and Solar Cells
Canadian institutionsnot available
Fundersnot available
KeywordsAqueous solutionPhotocatalysisPhotodegradationOxalateChemistryRadicalMontmorilloniteNuclear chemistryHydroxyl radicalInorganic chemistryCatalysisOrganic chemistry

Abstract

fetched live from OpenAlex

Photocatalytic decolourization of textile dye X3B in aqueous solutions was investigated, using iron-rich montmorillonite (MMt, 2.24%Fe 2 O 3 ) under a 15 W low-pressure UV lamp (λ = 254 nm, I = 48.4 μW/cm 2 ). Hydroxyl radicals ( • OH) were detected by tert-butyl alcohol (TBA) in aqueous MMt suspensions under UV irradiation and were found to be responsible for the degradation of X3B. Free iron ions dissolved in MMt suspensions, structural iron in the MMt solid, and the charged surface of nano clay are responsible for hydroxyl radical ( • OH) production. Low pH values are favorable for the decolourization of X3B. The • OH concentration increased with increasing aqueous MMt concentrations in the range of 0 – 2.0 g/L; higher concentrations, for example, 5.0 g/L MMt, inhibited the • OH production. The addition of oxalate was favorable for X3B photodegradation in acid-washed MMt suspensions. This study shows that iron-rich MMt is a potential photocatalyst for the treatment of dye wastewater.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.343
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.174
Teacher spread0.168 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2009
Admission routes1
Has abstractyes

Explore more

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