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Record W2042147398 · doi:10.1021/cm703052p

Discovery of Reversible Switching of Coloration of Passive Layers on Titanium

2008· article· en· W2042147398 on OpenAlexaff
Gregory Jerkiewicz, Baodong Zhao, Sabahudin Hrapovic, B. Luan

Bibliographic record

VenueChemistry of Materials · 2008
Typearticle
Languageen
FieldMaterials Science
TopicConducting polymers and applications
Canadian institutionsQueen's UniversityUniversité de Sherbrooke
Fundersnot available
KeywordsLayer (electronics)DissolutionMaterials scienceTitaniumGrowth rateVoltageIridescenceSteady state (chemistry)OptoelectronicsOpticsChemical engineeringComposite materialChemistryMetallurgyMathematicsElectrical engineering

Abstract

fetched live from OpenAlex

Colored passive layers on Ti can be prepared by electrochemical means and their coloration can be switched reversibly between several colors by increasing or decreasing the AC voltage ( V AC ) in a stepwise manner. The coloration, which originates from iridescence, is directly related to the passive layer’s thickness ( d ) achieved at each V AC value. Two concurrently occurring processes, the passive layer growth and passive layer dissolution, control the passive layer thickness. At a given AC voltage, the passive layer reaches a steady-state thickness at which the growth rate (υ growth ) equals the dissolution rate (υ diss ). An increase or decrease in V AC modifies the values of υ growth and υ diss until a new steady-state thickness, and new coloration, is achieved.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.000
Threshold uncertainty score0.267

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.247
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations30
Published2008
Admission routes1
Has abstractyes

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