Morphology in Immiscible Polymer Blends During Solidification of an Amorphous Dispersed Phase under Shearing
Bibliographic record
Abstract
Abstract Solidification under shear of dispersed polycarbonate (PC) fibers in copolymer polyethylene‐methyl acrylate matrix (EMA) was investigated using a hot optical shear device. First, the deformation of PC droplets and its modeling under isothermal conditions were studied for comprehension purposes. Overall agreement with literature models was found and the main influence of the viscosity ratio has been stressed. Second, the morphology control through dynamic quenching was experimented. It consists of solidifying the amorphous PC dispersed phase under shear flow. Break‐up times of PC fibers were taken into account. Shear rate and quenching‐time balance was demonstrated. Thus, during dynamic solidification, a fibrillar morphology could be obtained through rapid quenching. Long quenching times allow nodular morphology, whose size depends on the shear rate used. PC rods can be obtained by adjusting the shear rate during dynamic quenching.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".