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Record W2043891456 · doi:10.1021/jp063583t

Mesostructured Silica SBA-16 with Tailored Intrawall Porosity Part 2:  Diffusion

2007· article· en· W2043891456 on OpenAlexaff
Oliver C. Gobin, Qinglin Huang, Hoang Vinh‐Thang, Freddy Kleitz, Mladen Eić, Serge Kaliaguine

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2007
Typearticle
Languageen
FieldChemistry
TopicZeolite Catalysis and Synthesis
Canadian institutionsUniversité LavalUniversity of New Brunswick
Fundersnot available
KeywordsMesityleneCumenePorosityDiffusionVolume (thermodynamics)Work (physics)Materials scienceHeptaneChemical engineeringMineralogyThermodynamicsChemistryBenzeneComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

In this Part 2 of the present work, the diffusivities of n -heptane, cumene, and mesitylene in the SBA-16 silica samples described in Part 1 have been measured by the zero length column (ZLC) method. A comparison is made between the diffusivities and diffusion apparent activation energies in these materials and in a series of SBA-15 samples of similar pore size and pore volume. The latter series was discussed in a previous work. Clear differences are indeed observed and rationalized in terms of differences in the pore structure of the two series of solids.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.717

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.210
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations33
Published2007
Admission routes1
Has abstractyes

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