Photoluminescence Quenching of Nanocomposite Materials Used for Organic Solar Cells
Bibliographic record
Abstract
In this work, we have studied the photoluminescence (PL) quenching of two polymeric composites, poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) and poly(3-hexylthiophene) (P3HT) in presence of nc-TiO\(_{2}\) particles by PL- spectroscopy. PL quenching values are 19.2\(\text{\%}\) and 45.5\(\text{\%}\), for MEH-PPV+nc-TiO\(_{2}\) and P3HT+nc-TiO$_{2}$, respectively. The obtained results on the relationship of PL quenching and photoelectrical efficiency (PCE) of an OSC showed that the quenching coefficient of a semiconducting polymer can be considered as apreliminarycriterion for choosing an appropriate polymeric composite being used for OSC preparation. Under illumination of solar energyof 56 mW/cm\(^{2}\), P3HT+TiO\(_{2}\) based OSC possess FF, V$_{OC}$, J$_{SC}$ and PCE of 0.64, 0.243 V, 1.43 mA/cm\(^{2}\) and 0.45\(\text{\%}\), respectively.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".