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Record W2044990937 · doi:10.1021/es034644t

Polyfluorinated Telomer Alcohols and Sulfonamides in the North American Troposphere

2004· article· en· W2044990937 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueEnvironmental Science & Technology · 2004
Typearticle
Languageen
FieldEnvironmental Science
TopicPer- and polyfluoroalkyl substances research
Canadian institutionsUniversity of TorontoEnvironment and Climate Change Canada
Fundersnot available
KeywordsPerfluorooctaneChemistryTroposphereEnvironmental chemistryOrganic chemistryMeteorologyGeographySulfonate

Abstract

fetched live from OpenAlex

In 2001, a sampling campaign was conducted in six North American cities--Reno, NV; Griffin, GA; Cleves, OH; Winnipeg, MB; Long Point, ON; and Toronto, ON--to investigate the tropospheric distribution of a suite of polyfluorinated alcohols and amides. Analysis via gas chromatography-chemical ionization-mass spectrometry indicated that both polyfluorinated sulfonamides and fluorinated telomer alcohols (FTOHs) are widely distributed throughout the North American troposphere with mean concentrations ranging from 22 to 403 pg/m3 and from 11 to 165 pg/m3 respectively. The dominant polyfluorinated contaminant was dependent on sampling location. Large mean concentrations of N-methyl perfluorooctane sulfonamidoethanol (359 pg/m3) and N-ethyl perfluorooctane sulfonamidoethanol (199 pg/m3) identified in Griffin and Reno, respectively, may indicate the release of polyfluorinated sulfonamides to the environment through paper and carpet treatment processes. The nonuniform nature of the spatial distribution of both polyfluorinated sulfonamides and FTOHs is indicative of the importance of point sources for the dissemination of these contaminants in the North American troposphere.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.167
Threshold uncertainty score0.993

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.003
Science and technology studies0.0000.010
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.237
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it