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Record W2045222361 · doi:10.1007/s11746-010-1679-6

Evaluating Esters Derived from Mustard Oil (<i>Sinapis alba</i>) as Potential Diesel Additives

2010· article· en· W2045222361 on OpenAlexaff
Titipong Issariyakul, Ajay K. Dalai, Prabhat Desai

Bibliographic record

VenueJournal of the American Oil Chemists Society · 2010
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsUniversity of Saskatchewan
FundersSpace and Missile Defense Command
KeywordsBiodieselTransesterificationChemistryLubricityDiesel fuelOrganic chemistryVegetable oil refiningAlcoholCanolaMustard seedMethanolSoybean oilVegetable oilFood scienceCatalysis

Abstract

fetched live from OpenAlex

Abstract Biodiesel was produced from mustard oil utilizing transesterification with methanol, ethanol, propanol, and butanol to evaluate the characteristics of mustard biodiesel as an additive to regular diesel. Mustard oil was transesterified with alcohol at 6:1 alcohol to oil molar ratio, using KOH as a catalyst at 1 wt%. The maximum ester content achieved by this method was only 66%. Distillation was then used to purify the ester, raising the ester content to 99.8%. Alternatively, mustard oil methyl ester (MME) can be mixed with esters derived from canola oil or soybean oil to achieve an ASTM quality biodiesel. Biodiesel derived from mustard showed great potential as lubricity additive for regular diesel fuel. With an addition of 1% MME, lubricity of diesel fuel was improved by 43.7%. It is also found that methyl ester is the best lubricity additive among all esters (methyl‐, ethyl‐, propyl‐, and butyl‐ester). MME can be used at −16 °C without freezing whereas monounsaturated compounds (oleic, eicosenoic, and erucic esters) largely present in esters derived from mustard oil can tolerate −42 to −58 °C. Monounsaturated esters derived from higher alcohols such as butyl alcohol demonstrated a superior low temperature tolerance (−58 °C) as compared to that derived from lower alcohol such as methyl alcohol (−42 °C).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.264
Teacher spread0.252 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations36
Published2010
Admission routes1
Has abstractyes

Explore more

Same venueJournal of the American Oil Chemists SocietySame topicBiodiesel Production and ApplicationsFrench-language works237,207