USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS
Bibliographic record
Abstract
Irradiation of thin films of a polyketonate Pd/Ni heteronuclear complex, PdNi(DBA)2 [DBA = dibenzoylacetone)], produced uniform films containing Pd and Ni as shown by EDAX analysis. The X-ray powder diffraction spectrum showed peaks associated with elemental Pd and NiO. The morphology of the films was examined by SEM measurements showing a uniform granular surface with particle sizes of 100 nm or less. The XPS results show that the ratio of Pd/Ni (1:17) present in the film does reflect the stoichiometry in the starting complex. The large amount of carbon (52 %) detected on the surface of the film may be due to the presence of phenyl rings in the precursor complex.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".