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Record W2049056731 · doi:10.1002/pen.24060

<i>In situ</i> poly(sodium acrylate)‐based nanocomposite formation by redox‐initiated solution polymerization

2015· article· en· W2049056731 on OpenAlexafffund
Samaneh Khanlari, Marc A. Dubé

Bibliographic record

VenuePolymer Engineering and Science · 2015
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Nanocomposites and Properties
Canadian institutionsUniversity of Ottawa
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPolymerizationMaterials scienceNanocompositePolymer chemistryAcrylateIn situ polymerizationBiopolymerPolymerRadical polymerizationRedoxAqueous solutionChemical engineeringChemistryOrganic chemistryComposite materialCopolymer

Abstract

fetched live from OpenAlex

Polymer‐based nanocomposites have been widely investigated as a potential method to modify polymer and biopolymer properties. Poly(sodium acrylate) (PNaA)/nanosilver nanocomposites with 0.5, 1, 2, and 3 wt% nanofiller were prepared by in situ polymerization. The free radical, redox‐initiated, aqueous solution polymerization of NaOH‐neutralized acrylic acid was conducted in the presence of nanosilver. The progress of the polymerization was monitored using gravimetric conversion measurements. The addition of 0.5 wt% nanosilver to the polymerization resulted in a significant decrease in rate of polymerization The effect on rate was noticeably reduced when the experiment was repeated with nanoclay, a nonmetallic nanofiller, in lieu of nanosilver. POLYM. ENG. SCI., 55:1230–1236, 2015. © 2015 Society of Plastics Engineers

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.066
Threshold uncertainty score0.767

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.223
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2015
Admission routes2
Has abstractyes

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