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Record W2050341449 · doi:10.1021/ma2025732

Intrachain Ordering and Segregation of Polymers under Confinement

2012· article· en· W2050341449 on OpenAlex
Youngkyun Jung, Juin Kim, Suckjoon Jun, Bae‐Yeun Ha

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMacromolecules · 2012
Typearticle
Languageen
FieldMaterials Science
TopicPolymer crystallization and properties
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsPolymerPolymer scienceMaterials sciencePolymer chemistryChemical physicsChemistryComposite material

Abstract

fetched live from OpenAlex

We study the relationship between intrachain ordering and segregation tendency of two polymers confined in a cylindrical space. We find the chains segregate spontaneously even outside de Gennes’ linear-ordering scaling regime, in which each chain is a linear array of blobs. When the chains are weakly compressed against each other, linear ordering is well preserved and the chains remain segregated. On the other hand, for moderate compression, new chain-ordering units emerge at intermediate length scales, within which blobs are randomly packed; yet these units (termed “superblobs”) are linearly ordered, and the chains still segregate in the confined space. As the chains continue to be compressed, the linear regime disappears, but the chains can resist mixing effectively, more so in a more asymmetric space. We conclude that the linearly ordered E. coli chromosome is in the segregation regime.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.011
Threshold uncertainty score0.736

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.233
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it