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Record W2050767877 · doi:10.1021/es703114r

Optimization of a Biosorption Column Performance

2008· article· en· W2050767877 on OpenAlexaff
Ghinwa Naja, Bohumil Volesky

Bibliographic record

VenueEnvironmental Science & Technology · 2008
Typearticle
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsMcGill University
Fundersnot available
KeywordsBiosorptionSorptionMass transferChemistryDesorptionAdsorptionChromatographySorbentColumn (typography)Analytical Chemistry (journal)Yield (engineering)Simulated moving bedPressure dropMaterials scienceMechanicsMathematicsMetallurgyGeometry

Abstract

fetched live from OpenAlex

The dynamics of copper and zinc biosorption by Sargassum fluitans was analyzed under variable column operating conditions including different column lengths (15 and 45 cm), metal-feed solution concentrations (1 and 6 meq L(-1)), metal-sorbent affinities (2.01 and 0.45), and interstitial velocities (12 and 4 cm min(-1)). The experimental breakthrough curves obtained under these varying conditions were also simulated using a mathematical model taking into account the mass transfer as well as the axial dispersion phenomena. The column performance was evaluated using two performance indicators: the service time (t(s)) and the unused portion of the column as reflected in the area under the breakthrough curve (A(c)). Sensitivity analysis results indicated that the feed stream concentration, mass transfer coefficient, column length, and interstitial velocity had the most important effect on the column performance. Applying chromatography theories, the optimization of the biosorption process for productivity and sorption performance, in terms of operating conditions (interstitial velocity) and design parameters (column length), was outlined. The corresponding optimum curve relating the interstitial velocity and the column length resulted with the pressure drop limitations recognized. As an example, a laboratory column 100 cm long will necessitate an interstitial velocity of 19 cm min(-1) to yield the best sorption results.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.189
Teacher spread0.182 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations27
Published2008
Admission routes1
Has abstractyes

Explore more

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